the 805 wouldn't really be that much of a step up from your 3200+. There would be a few multithreaded apps that might take advantage of the dual cores, but smithfield's dual core performance is less than exciting, plus you have a tremendous clock speed disadvantage for single threaded applications. The 805 would need to be OC'd to like 3.8GHz in order to compete in stuff like games. Even at 3.2GHz, it would still be slower in single threaded apps, plus the FSB would only be 640MHz, meaning your memory bandwidth would be extremely bus limited, and Pentium Ds are very bandwidth hungry (goes with being a netburst chip).
As for the Core Duo, those are kinda nice, but right now they are mobile chips, and 32-bit only. That means desktop mobos are extremely rare - in fact, i only know of the one asus one, and thus will be expensive. The asus board also has very limited overclocking options.
Don't you think you'd be better off either:
1) selling your 3200+ and buying either an opty 165 or X2 3800+? These chips both OC pretty well, you can keep your existing mobo, and would be cheaper than a core duo + mobo and close to the same price as the 805 + mobo. I mean, i can see why you might want to jump ship to intel when they bring out conroe, but their current offerings aren't exactly that enticing.
2) keep your 3200+ and try OCing it further. my 3000+ winchester OC'd to 2.55GHz, i can't imagine a venice 3200+ being stuck at 2.4GHz. A fast single core will generally beat a slow dual core in most tasks. Besides, this option is free, and if it doesnt work, you can always try one of the other ones.