There is a flavor of 10/100 that uses all four pairs....
REF 1
Subject: 11.0 Standard Networking Configurations
With reference to T568B above;
ATM 155Mbps uses pairs 2 and 4 (pins 1-2, 7-8)
Ethernet 10Base-T uses pairs 2 and 3 (pins 1-2, 3-6)
Ethernet 100Base-T4 uses pairs 2 and 3 (4T+) (pins 1-2, 3-6)
Ethernet 100Base-T8 uses pairs 1,2,3 and 4 (pins 4-5, 1-2, 3-6, 7-8)
Token-Ring uses pairs 1 and 3 (pins 4-5, 3-6)
TP-PMD uses pairs 2 and 4 (pins 1-2, 7-8)
100VG-AnyLAN uses pairs 1,2,3 and 4 (pins 4-5, 1-2, 3-6, 7-8)
REF 2
100Base-T4 Facts
Transmission Rate 100 Mb/s (full-duplex not supported)
Cable Type four pairs of Category 3 or better unshielded twisted pair (UTP) cabling,
100-ohm impedance rating
Maximum Segment Length 100 meters (328 feet)
Maximum Number of Transceivers per Segment 2
Connecter Technology RJ-45 style modular jack (8-pins)
Signal Encoding 8B6T
The two references I have dont agree with each other except that there is a 'flavor' that uses all four pairs.