Originally posted by: Mookow
What is the mechanism behind the assumption that the ratio of C14 to C12 stays constant through time in the enviroment? Ditto with potassium.
<--- would put this in OT, but looking for a more in depth answer
statistical analysis. basically, they take samples of known materials, and look. and they saw a pattern. this ratio is no longer true if you go back no less than 100 years. or so. why? cuz we've been pumping out a massive amount of carbon dioxide. while the accuracy of carbon dating can be put into doubt, it is nontheless a valid method to gauge what is older than what, that is, something dated 100 million years old probably has a 10% error (+/- 5%) which is fairly insignificant.
carbon dating is very much based on statistics and recorded data. the formulae used in general chemistry and sciences that you learn in undergrad and prior are merely approximations and extrapolations which fall apart given some other data. how the age is given with respect to the real numbers you hear around the news are much more complicated than just comparing the ratio and plugging in the number. carbon dating dates often change because new statistical data causes the forumlae to change (this does not refer to the generalized approximation used in exponential decay, which is just an extrapolation or interpolation depending on how you look at it).
if you look at one team of carbon daters, and another, they will be similar but differ enough to show you that statistics is not as simple as 1+1 = 2.
to really answer the question ,there is no actual mechanism since statistics is used to approximate and extrapolate. it's better than pulling a number out of thin air, but it's not as good as having a written record.