Originally posted by: jhu
I don't understand why car batteries die. Aren't they essentially just two metal electrodes dipped in acid?
Here's what happens in one cell of a car's lead-acid battery (as an example of how all the cells work):
The cell has one plate made of lead and another plate made of lead dioxide, with a strong sulfuric acid electrolyte in which the plates are immersed.
Lead combines with SO4 (sulfate) to create PbSO4 (lead sulfate), plus one electron.
Lead dioxide, hydrogen ions and SO4 ions, plus electrons from the lead plate, create PbSO4 and water on the lead dioxide plate.
As the battery discharges, both plates build up PbSO4 and water builds up in the acid. The characteristic voltage is about 2 volts per cell, so by combining six cells you get a 12-volt battery.
A lead-acid battery has a nice feature -- the reaction is completely reversible. If you apply current to the battery at the right voltage, lead and lead dioxide form again on the plates so you can reuse the battery over and over.