I don't use iChat so I am not sure if there is a way. Maybe if you install Chax? it is a plugin for iChat that I think still works, but it would be best if Tyranicus showed up, he actually uses iChat.
Adium will do it, but Adium will not do ScreenSharing or Video/Audio chats, and sometimes gets wonky on file transfers.
Originally posted by: Tyranicus
I don't know how to do it automatically either. I've done it manually for my contacts. if someone figures this out, I would like to know as well.
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