Whatcha going to use the PVC for? Air? Liquid? Something else???
Be sure and use the primer (purple colored) BEFORE applying ANY cement. If you're going to use it for liquid, I'd recommend the "Rain -r- Shine" cement. I've used that with good results. If you intend to use the PVC for an air line for a compressor, DON'T! It's not pretty when the pipe lets go.