Not really.
It's not very tricky either, but then I've been doing it for a while.
You should really BE concerned when you have problems booting with a RAID-array. That usually means that either you've lost enough drives to fail the array or that somehow the information on it has become corrupted (RAID-information is kept on HD's - they can get corrupted).
But, that's so rare nowadays ... I'd take RAID over "normal" SCSI any day

. Esp. when I don't have to pay for it ;D.
Why? Have you got reason to be concerned or are you just considering getting a RAID-array?