If his speaker supports it and his receiver supports it, why not?
Passive bi-amping does little to improve the sound quality since the tweeter uses so little power compared to the woofer. Providing power to the individual drivers separately does not add much headroom at all compared to providing the same power to the drivers with the straps connecting the binding posts. It is mainly there because customers like to see 4 binding posts and wire companies make a huge profit on their cables.
As a overly simplistic example (best case scenario), 100W + 100W bi-amp allows each driver to see 100W. However, the tweeter typically only uses 10 Watts before catching fire, so that extra 90W does nothing; the Woofer uses up to ~100 Watts (assuming it can handle 100 Watts).
100W normal hook up with straps connecting the binding posts: As in the above example, the woofer receives up to ~90 Watts which gives you ~0.5dB less headroom than the bi-amp hypothetical, hardly audible especially when at the limits of the speaker.
At normal sound pressure levels, you will be lucky if the tweeter is drawing more than 3-5 Watts.
To answer the OP's question, I would assume the top binding posts correspond to the tweeter, and the bottom binding posts correspond to the woofer.