TIM pumpout is when repeated heat cycling eventually causes the TIM to migrate and degrade in performance over time.
In my case, it is a difference of around 15C once it gets bad. It happens under my IHS with NT-H1 pretty badly.
TIM choices I have:
AS5
Antec Formula 5 (no clue where this came from)
NT-H1
1 more application of IX.
I am tempted to somehow figure out how to make the IX work on the bare die (maybe with a shim to insulate the non-die portion of the cpu).
I don't know if I'm that brave. I do have somewhat of a lemon of a 3770k, so it wouldn't be a huge loss if I destroyed it in the attempt. I would basically have to mask off everything but the die estimate the amount needed, plop it on to the center of the die, and go from there.
That seems risky to me, but potentially interesting.
edit: maybe high-temp caulk?