ATA33 was like driving a vespa on a dirt road. ATA66 paved the road, ATA 100 widened it, and ATA100 made it 4 lanes. ATA133 adds a little more, but you're still drivin' a vespa, so it doesn't matter much.
The ATA100 standard added some under the surface improvements having to do with error checking &etc, and is part of the reason it was quickly adopted. Unless ATA 133 does more of this kind of stuff, it doesn't seem like much of an improvement to me....