It sucks, don't use it.
A former employer loved it for some reason, used it for all major company meetings, and it never, ever worked 100% right. At a minimum, it required Windows, IE, and default wide-open security settings, or your client couldn't do anything. Even then, reliability was lacking and performance was sllow. I was told that it was expensive, too.
Everything they did with WebEx could have been done using freely available tools. In their case, VNC could have done it all - it was just PowerPoint screen sharing. I think WebEx can do more than that, and so I suggest you investigate what freely available tools could do what you are trying to use WebEx to do.
"I've been asked to allow vendors to remote control into the company, to workstations/servers." I'm not sure why you'd use WebEx for this problem. Could you elaborate as to the problem you're trying to solve? Maybe we could suggest a better solution that way.
At a high level, letting vendors remote control into company machines is already a nervous place. It sounds to me like you should put the affected machines into their own special sandbox network, quite firewalled from the rest of your corporate infrastructure, and make sure you have appropriate access controls and policy controls in place, not to mention legal CYA.