At work , we use Avaya PBX ( G3r ) and Avaya Cajun/Cisco 6500 switches . Work great with one remote call center location ( 5 miles away ) with one T3 for both data and voice over ip for the last 18 month along with one separate T1 as backup. You can not tell any different in term of voice quality wise . I was skeptical at first but the technology is here and it save us lots of money from buying another PBX / T1 voice line . Currently we process about 30,000 calls on a light day without any prob on this T3 .
I don't know much about vonage since we are strictly Avaya shop voice wise