YOu've got to understand that digestion is much more than the body trying to buffer the acidic partly digested food from the stomach at the duodenum. The duodenum is also where bile, with its alkaline bile salts, and pancreatic juices, which have a pH of around 8.4-8.9, enter the digestive system. I'd think there is not enough time for bicarb, which is a very slow acting buffer in the body the way the body's system is set up in a negative feedback system, to try to buffer the digestive juices, nor would it want to at that early stage in the intestines due to the introduction of the aforementioned salts and such.