I am glad that tweaker2 and Fenixgoon add in new understanding of metallurgy. But still this whole thread has lead to little common thread user understanding of why some steels harden and why.
But still there is a division in human history, known by the stone age, the bronze age, and the iron age now somewhat lost in ancient antiquity more than 2 millennium before the current age.
And I somewhat ask why steel making is a mature process, when mankind didn't learn to even learn to make decent pure iron in large lots before the invention of the Bessemer converter furnaces circa 1865.
But as a metal with any decent mechanical properties, pure iron is really inferior. So why should the addition of carbon in varying amounts change the properties a steel? And how much Carbon to add before it becomes counter productive, and we get a weaker cast iron instead greatly inferior in tensile strength?
But anyone who studies metallurgy understands why steel allows us to have our cake and eat it too. As we can easily machine a soft steel and harden it later.
Because the secret in steel hardening is in the allotropic properties of the Iron Crystals. Below about 1320 F Iron forms in to body centered crystals, with fewer basic atoms of iron, above 1320 F the iron crystals transform into a Face centered crystal taking more iron atoms per crystal, Leaving the center hollow and open for small atoms like Carbon. Cool it slowly and we get no hardening, cool it quickly and it screws up all the crystalline slip planes as the expelled carbon forms needle like structures called martensite. So it goes for the 1000 series of steels. As we trade off hardness for brittleness. But still as a weakening agent, we still retain some FCC crystals called Austinite. The seeming secret of super Banite is very little retained Austinite. But still its now designer steel of precise composition, that relies far less on just carbon for hardening and perhaps can only be made in more expensive electric arc furnaces that allow more precise control of other hardening agents such as molybdenum, chrome, vanadium, and other goodies not refined out by basic basic oxygen furnaces. So we get subsequent lots of pre-heated steels with unknown compositions. One lot may be easily machinable, the next lot may be harder than hammered hell, as a toolmaker, it used to drive my company nuts. Get too much of something in the steel, and it would air harden into something super hard to machine.
Most other metals do not have allotropic crystals so they can only be hardened by participation hardening methods or coatings.