Go to the area you want to add a folder. Right click and pick new folder. Rename it into the folder name you want.
So for your example, you would go to the E drive. Create a new folder and then rename it Program Files.
actually this is quite simple with a built in command to xp. there is a command called subst that will create a virtual drive to a folder that you specify...
basically if you want to have c:\blah as say z: in my computer you would do this:
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