DO NOT BUY 2x6600GT.
Reasons: It won't be much cheaper if you buy now than a 6800GT (with the premium for an SLI mobo).
6800GT's can be had for MSRP (yes, it IS a reason). Not too bad a price.
6600GT in SLI WILL NOT beat a 6800GT. - To explain. Most tests show it about equal. Most tests, not with AA/AF. Also take into account the fact that not all games will run in SLI, IIRC, so sometimes you will only have the power of a 6600GT single. This is reason enough to get a 6800GT which will ALWAYS perform, as it does not require SLI.
You could also always get a 6800GT now and then another down the line, if you get an SLI mobo.
Surprisingly enough, throughout all of our testing, we didn?t encounter any rendering issues in SLI mode. NVIDIA insists that they have tested quite a few of the top 100 games to ensure that there aren?t any issues with SLI mode and it does seem that they?ve done a good job with their driver. If the driver hasn?t been profiled with a game, it will default to single-GPU mode to avoid any rendering issues, but the user can always force SLI mode if they wish.
There's a risk of issues when forcing SLI sometimes, so a 6800GT over 6600GT will be better.