A 32-bit/33MHz PCI slot allows 133MB/s of throughput. A 64-bit/33MHz slot allows 266MB/s. A 64-bit/66Mhz allows 533MB/s.
If the hard drives are the same, add up all the burst transfer rates and divide by two. If the number is greater than 133, then to see the best performance you should move to a motherboard with 64-bit slots. If the number is less than 133, then you won't see any performance limitations.