Upgrading just a ram on a most systems won't do much.
It's kinda like getting a performance air filter for a car.. there is a performance gain, but will it make the car zoom? no.. (crude analogy i know..

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ram upgrade performance on your system is mostly in the "numbers", and doesn't really account much in "real" time.
To see real time performance gain, you'll have to upgrade more parts, which isn't recommended on your mobo.
As I said before, if you have to spend money on it, then it's not worth it to upgrade on ECS mobo..
But as far as just the ram goes, if you do the rebate and end up getting those DDRs for free then I guess why not keep em.