Would the 2 SSD's be better used separately so that both disks can work on separate tasks at the same time or as a RAID 0.
I'd say to keep things easy on yourself. You're not going to notice much difference in Raid-0, whereas you will notice a bigger difference with the newer controllers out there.
Also, I'm not a tweaker or a power user, so, if Trim is unavailable for RAID 0 should I steer clear of it?
If you're not a tweaker or a power user, again, stay away from Raid 0. Raid-0 was really beneficial for HDDs and early SSDs. You saw a significant improvement for HDDs, but you always chanced a failure, which I encountered several on my 4xRaptor setup. Sure, if you RAID your SSDs there might be some improvement, but those will mostly be in the numbers. That's like trying to get your system to open up MS Word to the fastest nano-second, which really is of no consequence to the average user, or even most power users, just enthusiasts.
My Next Setup
What I'm planning to do for my next setup, which may help you:
-
System/Application Disks: 2 x SSD (256GB-512GB)
-
Temp Storage Disk: 1 x SSD (~30GB)
-
Media Disks: ? x HDD (2-5TB)
-
Backup Disks: ? x HDD (5-10TB) / Possibly Raided-NAS (not Raid-0)
The important thing to take away is the Temp storage disk, which I plan to put temp/scratch/page file/hibernation/local-backup kind of data on. Why? Only to do some pre-emptive filtering, to extend the life of the main drives.
Even if the life expectancies aren't supposed to be that bad (supposed to last a while), I still don't trust ratings; especially, new devices that are rated for lifespans, which are longer than the product has even been around. There are two many electro-mechanical phenomenon that exist (magnetism, thermals, use) that may screw a drive up over it's rated lifespan. So having a temporary disk, which should crap out before the main drives not only gives you a heads up/warning to ensure you have good backups, but it is data that you can more afford to lose, if the drive has met it's maximum use.